.. Calcul-de-la-fonction-de-projection, 48 Estimation de la distance bord-à-bord, p.49

.. Estimation-de-la-distance-interparticule-selon-les-différentes-chimies-de-surface, 129 5.3.1 Calibration de la relation entre la longueur d'onde de résonance et la distance interparticule, p.129

D. Patrick, O. Neal, L. R. Hirsch, N. J. Halas, J. D. Payne et al., Photo-thermal tumor ablation in mice using near infrared-absorbing nanoparticles, Cancer Letters, vol.209, issue.2, pp.171-176, 2004.

Y. Seol, A. E. Carpenter, and T. T. Perkins, Gold nanoparticles: enhanced optical trapping and sensitivity coupled with significant heating, Optics Letters, vol.31, issue.16, pp.312429-2431, 2006.
DOI : 10.1364/OL.31.002429

H. Ivan, X. El-sayed, M. A. Huang, and . El-sayed, Selective laser photothermal therapy of epithelial carcinoma using anti-EGFR antibody conjugated gold nanoparticles, Cancer Letters, vol.239, issue.1, pp.129-135, 2006.

X. Huang, I. H. El-sayed, W. Qian, and A. Mostafa, Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods, Journal of the American Chemical Society, vol.128, issue.6, pp.2115-2120, 2006.
DOI : 10.1021/ja057254a

A. Agarwal, S. W. Huang, M. O. Donnell, K. C. Day, M. Day et al., Targeted gold nanorod contrast agent for prostate cancer detection by photoacoustic imaging, Journal of Applied Physics, vol.102, issue.6, p.64701, 2007.
DOI : 10.1063/1.2777127

K. Prashant, K. Jain, I. H. Seok-lee, . El-sayed, and A. Mostafa, El-Sayed. Calculated Absorption and Scattering Properties of Gold Nanoparticles of Different Size, Shape, and Composition : Applications in Biological Imaging and Biomedicine, J. Phys. Chem. B, issue.14, pp.1107238-7248, 2006.

R. Gref, . Lück, . Quellec, . Marchand, . Dellacherie et al., ???Stealth??? corona-core nanoparticles surface modified by polyethylene glycol (PEG): influences of the corona (PEG chain length and surface density) and of the core composition on phagocytic uptake and plasma protein adsorption, Colloids and Surfaces B: Biointerfaces, vol.18, issue.3-4, pp.3-4301, 2000.
DOI : 10.1016/S0927-7765(99)00156-3

D. Adam, R. P. Mcfarland, and . Van-duyne, Single Silver Nanoparticles as Real- Time Optical Sensors with Zeptomole Sensitivity, Nano Lett, vol.3, issue.8, pp.1057-1062, 2003.

G. Raschke, S. Kowarik, T. Franzl, C. Sönnichsen, T. A. Klar et al., Biomolecular Recognition Based on Single Gold Nanoparticle Light Scattering, Nano Letters, vol.3, issue.7, pp.935-938, 2003.
DOI : 10.1021/nl034223+

P. Zijlstra, P. M. Paulo, and M. Orrit, Optical detection of single non-absorbing molecules using the surface plasmon resonance of a gold nanorod, Nature Nanotechnology, vol.7, issue.6, pp.379-382, 2012.
DOI : 10.1021/cm020732l

I. Ament, J. Prasad, A. Henkel, S. Schmachtel, and C. Sönnichsen, Single Unlabeled Protein Detection on Individual Plasmonic Nanoparticles, Nano Letters, vol.12, issue.2, pp.1092-1095, 2012.
DOI : 10.1021/nl204496g

W. Rechberger, A. Hohenau, A. Leitner, J. R. Krenn, B. Lamprecht et al., Optical properties of two interacting gold nanoparticles, Optics Communications, vol.220, issue.1-3, pp.1-3137, 2003.
DOI : 10.1016/S0030-4018(03)01357-9

C. A. Mirkin, R. L. Letsinger, R. C. Mucic, and J. J. Storhoff, A DNA-based method for rationally assembling nanoparticles into macroscopic materials, Nature, vol.382, issue.6592, pp.382607-609, 1996.
DOI : 10.1038/382607a0

R. Elghanian, J. J. Storhoff, R. C. Mucic, R. L. Letsinger, and C. A. Mirkin, Selective Colorimetric Detection of Polynucleotides Based on the Distance-Dependent Optical Properties of Gold Nanoparticles, Science, vol.277, issue.5329, pp.2771078-1081, 1997.
DOI : 10.1126/science.277.5329.1078

C. Sönnichsen, M. Björn, J. Reinhard, and . Liphardt, A molecular ruler based on plasmon coupling of single gold and silver nanoparticles, Nature Biotechnology, vol.88, issue.6, pp.741-745, 2005.
DOI : 10.1002/anie.200390075

M. Björn, M. Reinhard, H. Siu, A. Agarwal, J. Paul-alivisatos et al., Calibration of Dynamic Molecular Rulers Based on Plasmon Coupling between Gold Nanoparticles, Nano Lett, vol.5, issue.11, pp.2246-2252, 2005.

K. Prashant, W. Jain, M. A. Huang, and . El-sayed, On the Universal Scaling Behavior of the Distance Decay of Plasmon Coupling in Metal Nanoparticle Pairs : A Plasmon Ruler Equation, Nano Lett, vol.7, issue.7, pp.2080-2088, 2007.

A. P. Alivisatos, K. P. Johnsson, X. Peng, T. E. Wilson, C. J. Loweth et al., Organization of 'nanocrystal molecules' using DNA, Nature, vol.382, issue.6592, pp.382609-611, 1996.
DOI : 10.1038/382609a0

D. Zanchet, C. M. Micheel, W. J. Parak, D. Gerion, and A. Paul-alivisatos, Electrophoretic Isolation of Discrete Au Nanocrystal/DNA Conjugates, Nano Letters, vol.1, issue.1, pp.32-35, 2001.
DOI : 10.1021/nl005508e

P. Mickaël, B. Busson, B. Rolly, N. Stout, E. Bonod et al., Optical and Topological Characterization of Gold Nanoparticle Dimers Linked by a Single DNA Double Strand, Nano Lett, vol.11, issue.11, pp.5060-5065, 2011.

S. Tyagi and F. R. Kramer, Molecular Beacons: Probes that Fluoresce upon Hybridization, Nature Biotechnology, vol.13, issue.3, pp.303-308, 1996.
DOI : 10.1073/pnas.93.18.9881

M. M. Maye, M. Thilak-kumara, D. Nykypanchuk, W. B. Sherman, and O. Gang, Switching binary states of nanoparticle superlattices and dimer clusters by DNA strands, Nature Nanotechnology, vol.108, issue.2, pp.116-120, 2010.
DOI : 10.1038/nnano.2009.378

I. L. Jennifer, Y. Chen, D. S. Chen, and . Ginger, Plasmonic Nanoparticle Dimers for Optical Sensing of DNA in Complex Media, J. Am. Chem. Soc, vol.132, issue.28, pp.9600-9601, 2010.

T. A. Larson, P. P. Joshi, and K. Sokolov, a Hydrophobic Shield, ACS Nano, vol.6, issue.10, pp.9182-9190, 2012.
DOI : 10.1021/nn3035155

P. Christopher, Toumey and Philosophy Documentation Center Reading Feynman Into Nanotechnology : A Text for a New Science, Techné : Research in Philosophy and Technology, vol.12, issue.3, pp.133-168, 2008.

T. Mappes, N. Jahr, A. Csaki, N. Vogler, J. Popp et al., The Invention of Immersion Ultramicroscopy in 1912-The Birth of Nanotechnology?, Angewandte Chemie International Edition, vol.316, issue.45, pp.11208-11212, 2012.
DOI : 10.1002/anie.201204688

I. Freestone, N. Meeks, M. Sax, and C. Higgitt, The Lycurgus Cup ??? A Roman nanotechnology, Gold Bulletin, vol.9, issue.4, pp.270-277, 2007.
DOI : 10.1007/BF03215599

M. Daniel and D. Astruc, Gold Nanoparticles:?? Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology, Chemical Reviews, vol.104, issue.1, pp.293-346, 2004.
DOI : 10.1021/cr030698+

D. Thompson, Michael Faraday's recognition of ruby gold: the birth of modern nanotechnology, Gold Bulletin, vol.40, issue.4, pp.267-269, 2007.
DOI : 10.1007/BF03215598

J. Turkevich, Colloidal gold. Part II, Gold Bulletin, vol.81, issue.4, pp.125-131, 1985.
DOI : 10.1007/BF03214694

P. Peter, J. Edwards, and . Thomas, Gold in a Metallic Divided State?From Faraday to Present-Day Nanoscience, Angewandte Chemie International Edition, vol.46, issue.29, pp.5480-5486, 2007.

S. J. Barrow, A. M. Funston, D. E. Gómez, T. J. Davis, and P. Mulvaney, Surface Plasmon Resonances in Strongly Coupled Gold Nanosphere Chains from Monomer to Hexamer, Nano Letters, vol.11, issue.10, pp.4180-4187, 2011.
DOI : 10.1021/nl202080a

C. C. Lam, P. T. Leung, and K. Young, Explicit asymptotic formulas for the positions, widths, and strengths of resonances in Mie scattering, Journal of the Optical Society of America B, vol.9, issue.9, pp.1585-1592, 1992.
DOI : 10.1364/JOSAB.9.001585

A. Wokaun, J. P. Gordon, and P. F. Liao, Radiation Damping in Surface-Enhanced Raman Scattering, Physical Review Letters, vol.48, issue.14, pp.957-960, 1982.
DOI : 10.1103/PhysRevLett.48.957

H. Robert, P. Doremus, and . Rao, Optical properties of nanosized gold particles, Journal of Materials Research, vol.11, issue.11, pp.2834-2840, 1996.

U. Kreibig and L. Genzel, Optical absorption of small metallic particles, Surface Science, vol.156, issue.2, pp.678-700, 1985.
DOI : 10.1016/0039-6028(85)90239-0

M. Meier and A. Wokaun, Enhanced fields on large metal particles: dynamic depolarization, Optics Letters, vol.8, issue.11, pp.581-583, 1983.
DOI : 10.1364/OL.8.000581

C. Nadrian and . Seeman, DNA in a material world, Nature, issue.6921, pp.421427-431, 2003.

C. Nadrian and . Seeman, Nanomaterials Based on DNA, Annu Rev Biochem, vol.79, pp.65-87, 2010.

R. Charles, D. T. Martin, and . Mitchell, Peer Reviewed : Nanomaterials in Analytical Chemistry, Anal. Chem, vol.70, issue.9, pp.322-327, 1998.

L. Novotny and B. Hecht, Principles of Nano-Optics, 2012.

S. A. Maier, Plasmonics : Fundamentals and Applications : Fundamentals and Applications, 2007.

F. Craig, D. R. Bohren, and . Huffman, Absorption and Scattering of Light by Small Particles, 2008.

W. Cai, H. Hofmeister, and M. Dubiel, Importance of lattice contraction in surface plasmon resonance shift for free and embedded silver particles, The European Physical Journal D, vol.13, issue.2, pp.245-253, 2001.
DOI : 10.1007/s100530170273

H. Hövel, S. Fritz, A. Hilger, U. Kreibig, and M. Vollmer, Width of cluster plasmon resonances : Bulk dielectric functions and chemical interface damping, Phys. Rev. B, issue.24, pp.4818178-18188, 1993.

J. Tiggesbäumker, L. Köller, K. Meiwes-broer, and A. Liebsch, Blue shift of the Mie plasma frequency in Ag clusters and particles, Physical Review A, vol.48, issue.3, pp.1749-1752, 1993.
DOI : 10.1103/PhysRevA.48.R1749

R. Cao, C. A. Jin, and . Mirkin, DNA-Modified Core???Shell Ag/Au Nanoparticles, Journal of the American Chemical Society, vol.123, issue.32, pp.7961-7962, 2001.
DOI : 10.1021/ja011342n

K. Prashant, M. A. Jain, and . El-sayed, Universal Scaling of Plasmon Coupling in Metal Nanostructures : Extension from Particle Pairs to Nanoshells, Nano Lett, vol.7, issue.9, pp.2854-2858, 2007.

U. Håkanson, M. Agio, S. Kühn, L. Rogobete, T. Kalkbrenner et al., Coupling of plasmonic nanoparticles to their environments in the context of van der Waals???Casimir interactions, Physical Review B, vol.77, issue.15, p.77155408, 2008.
DOI : 10.1103/PhysRevB.77.155408

V. Vitaly and . Kresin, Collective resonances in silver clusters : Role of d electrons and the polarization-free surface layer, Phys. Rev. B, vol.51, issue.3, pp.1844-1849, 1995.

T. R. Jensen, M. L. Duval, K. L. Kelly, A. A. Lazarides, G. C. Schatz et al., Nanosphere Lithography:?? Effect of the External Dielectric Medium on the Surface Plasmon Resonance Spectrum of a Periodic Array of Silver Nanoparticles, The Journal of Physical Chemistry B, vol.103, issue.45, pp.9846-9853, 1999.
DOI : 10.1021/jp9926802

J. Y. Bigot, J. Y. Merle, O. Cregut, and A. Daunois, Electron Dynamics in Copper Metallic Nanoparticles Probed with Femtosecond Optical Pulses, Physical Review Letters, vol.75, issue.25, pp.4702-4705, 1995.
DOI : 10.1103/PhysRevLett.75.4702

J. Martin, M. Kociak, Z. Mahfoud, J. Proust, D. Gérard et al., High-Resolution Imaging and Spectroscopy of Multipolar Plasmonic Resonances in Aluminum Nanoantennas, Nano Letters, vol.14, issue.10, pp.5517-5523, 2014.
DOI : 10.1021/nl501850m

L. Wu and B. M. Reinhard, Probing subdiffraction limit separations with plasmon coupling microscopy: concepts and applications, Chemical Society Reviews, vol.34, issue.11, pp.3884-3897, 2014.
DOI : 10.1039/c3cs60340g

J. Lermé, H. Baida, C. Bonnet, M. Broyer, E. Cottancin et al., Size Dependence of the Surface Plasmon Resonance Damping in Metal Nanospheres, The Journal of Physical Chemistry Letters, vol.1, issue.19, pp.2922-2928, 2010.
DOI : 10.1021/jz1009136

H. Baida, P. Billaud, S. Marhaba, D. Christofilos, E. Cottancin et al., Nanoparticles, Sánchez-Iglesias, I. Pastoriza-Santos, and L. M. Liz-Marzán. Quantitative Determination of the Size Dependence of Surface Plasmon Resonance Damping in Single Ag@SiO2 Nanoparticles, pp.3463-3469, 2009.
DOI : 10.1021/nl901672b
URL : https://hal.archives-ouvertes.fr/hal-00676439

A. Kawabata and R. Kubo, Electronic Properties of Fine Metallic Particles. II. Plasma Resonance Absorption, Journal of the Physical Society of Japan, vol.21, issue.9, pp.1765-1772, 1966.
DOI : 10.1143/JPSJ.21.1765

L. Genzel and U. Kreibig, Dielectric function and infrared absorption of small metal particles, Zeitschrift f???r Physik B Condensed Matter and Quanta, vol.10, issue.2, pp.93-101, 1980.
DOI : 10.1007/BF01365365

C. Voisin, N. D. Fatti, D. Christofilos, and F. Vallée, Ultrafast Electron Dynamics and Optical Nonlinearities in Metal Nanoparticles, The Journal of Physical Chemistry B, vol.105, issue.12, pp.2264-2280, 2001.
DOI : 10.1021/jp0038153

J. A. Scholl, A. L. Koh, and J. A. Dionne, Quantum plasmon resonances of individual metallic nanoparticles, Nature, vol.10, issue.7390, pp.421-427, 2012.
DOI : 10.1038/nature10904

M. Rycenga, C. M. Cobley, J. Zeng, W. Li, C. H. Moran et al., Controlling the Synthesis and Assembly of Silver Nanostructures for Plasmonic Applications, Chemical Reviews, vol.111, issue.6, pp.3669-3712, 2011.
DOI : 10.1021/cr100275d

K. S. Yee, Numerical solution of initial boundary value problems involving Maxwell's equations in isotropic media, IEEE Trans. Antennas and Propagation, pp.302-307, 1966.

T. Bruce, P. J. Draine, and . Flatau, Discrete-Dipole Approximation For Scattering Calculations, J. Opt. Soc. Am. A, vol.11, issue.4, pp.1491-1499, 1994.

P. Nordlander, C. Oubre, E. Prodan, K. Li, and M. I. Stockman, Plasmon Hybridization in Nanoparticle Dimers, Nano Letters, vol.4, issue.5, pp.899-903, 2004.
DOI : 10.1021/nl049681c

K. Su, Q. Wei, X. Zhang, J. J. Mock, D. R. Smith et al., Interparticle Coupling Effects on Plasmon Resonances of Nanogold Particles, Nano Letters, vol.3, issue.8, pp.1087-1090, 2003.
DOI : 10.1021/nl034197f

S. A. Maier, M. L. Brongersma, P. G. Kik, and H. A. Atwater, Observation of near-field coupling in metal nanoparticle chains using far-field polarization spectroscopy, Physical Review B, vol.65, issue.19, p.65193408, 2002.
DOI : 10.1103/PhysRevB.65.193408

M. Björn, S. Reinhard, A. Sheikholeslami, A. Mastroianni, J. Paul-alivisatos et al., Use of plasmon coupling to reveal the dynamics of DNA Références bending and cleavage by single EcoRV restriction enzymes, pp.2667-2672, 2007.

L. Yang, H. Wang, B. Yan, and B. M. Reinhard, Calibration of Silver Plasmon Rulers in the 1???25 nm Separation Range: Experimental Indications of Distinct Plasmon Coupling Regimes, The Journal of Physical Chemistry C, vol.114, issue.11, pp.4901-4908, 2010.
DOI : 10.1021/jp911858v

L. Gunnarsson, T. Rindzevicius, J. Prikulis, B. Kasemo, M. Käll et al., Confined Plasmons in Nanofabricated Single Silver Particle Pairs:?? Experimental Observations of Strong Interparticle Interactions, The Journal of Physical Chemistry B, vol.109, issue.3, pp.1079-1087, 2005.
DOI : 10.1021/jp049084e

K. Prashant, M. A. Jain, and . El-sayed, Plasmonic coupling in noble metal nanostructures, Chemical Physics Letters, vol.487, issue.46, pp.153-164, 2010.

B. Khlebtsov, A. Melnikov, V. Zharov, and N. Khlebtsov, Absorption and scattering of light by a dimer of metal nanospheres: comparison of dipole and multipole approaches, Nanotechnology, vol.17, issue.5, p.1437, 2006.
DOI : 10.1088/0957-4484/17/5/045

B. Rolly, B. Stout, and N. Bonod, Metallic dimers: When bonding transverse modes shine light, Physical Review B, vol.84, issue.12, p.125420, 2011.
DOI : 10.1103/PhysRevB.84.125420
URL : https://hal.archives-ouvertes.fr/hal-01281220

S. Y. Suck, S. Collin, N. Bardou, Y. De-wilde, and G. Tessier, Imaging the three-dimensional scattering pattern of plasmonic nanodisk chains by digital heterodyne holography, Optics Letters, vol.36, issue.6, pp.849-851, 2011.
DOI : 10.1364/OL.36.000849

H. Xu, A new method by extending Mie theory to calculate local field in outside/inside of aggregates of arbitrary spheres, Physics Letters A, vol.312, issue.5-6, pp.5-6411, 2003.
DOI : 10.1016/S0375-9601(03)00687-X

S. Marhaba, G. Bachelier, C. Bonnet, M. Broyer, E. Cottancin et al., Surface Plasmon Resonance of Single Gold Nanodimers near the Conductive Contact Limit, The Journal of Physical Chemistry C, vol.113, issue.11, pp.4349-4356, 2009.
DOI : 10.1021/jp810405y

A. Curry, G. Nusz, A. Chilkoti, and A. Wax, Substrate effect on refractive index dependence of plasmon resonance for individual silver nanoparticles observed using darkfield microspectroscopy, Optics Express, vol.13, issue.7, p.2668, 2005.
DOI : 10.1364/OPEX.13.002668

W. Huang, W. Qian, P. K. Jain, and M. A. El-sayed, The Effect of Plasmon Field on the Coherent Lattice Phonon Oscillation in Electron-Beam Fabricated Gold Nanoparticle Pairs, Nano Letters, vol.7, issue.10, pp.3227-3234, 2007.
DOI : 10.1021/nl071813p

J. Bruce, R. Berne, and . Pecora, Dynamic Light Scattering : With Applications to Chemistry, Biology, and Physics, 2000.

R. G. Julien, M. H. Navarro, and . Werts, Resonant light scattering spectroscopy of gold, silver and gold?silver alloy nanoparticles and optical detection in microfluidic channels, Analyst, vol.138, issue.2, pp.583-592, 2012.

N. Jacob and . Israelachvili, Intermolecular and Surface Forces : Revised Third Edition, 2011.

J. Wu, D. Bratko, and J. M. Prausnitz, Interaction between likecharged colloidal spheres in electrolyte solutions, pp.9515169-15172, 1998.

B. Derjaguin and L. Landau, Theory of the stability of strongly charged lyophobic sols and of the adhesion of strongly charged particles in solutions of electrolytes, Progress in Surface Science, vol.43, issue.1-4, pp.1-430, 1993.
DOI : 10.1016/0079-6816(93)90013-L

E. , W. Verwey, J. Th, G. Overbeek, J. T. et al., Theory of the Stability of Lyophobic Colloids, 1999.

B. Beresford-smith, D. Y. Chan, and D. Mitchell, The electrostatic interaction in colloidal systems with low added electrolyte, Journal of Colloid and Interface Science, vol.105, issue.1, pp.216-234, 1985.
DOI : 10.1016/0021-9797(85)90362-5

M. J. Grimson and M. Silbert, A self-consistent theory of the effective interactions in charge-stabilized colloidal dispersions, Molecular Physics, vol.74, issue.2, pp.397-404, 1991.
DOI : 10.1039/f29848000141

R. Van, R. , and J. Hansen, Van der Waals?Like Instability in Suspensions of Mutually Repelling Charged Colloids, Phys. Rev. Lett, vol.79, issue.16, pp.3082-3085, 1997.

R. A. Sperling and W. J. Parak, Surface modification, functionalization and bioconjugation of colloidal inorganic nanoparticles, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.128, issue.15, pp.1333-1383, 1915.
DOI : 10.1021/ja060782h

T. Sakura, T. Takahashi, K. Kataoka, and Y. Nagasaki, One-pot preparation of mono-dispersed and physiologically stabilized gold colloid, Colloid and Polymer Science, vol.74, issue.4, pp.97-101, 2005.
DOI : 10.1007/s00396-005-1339-9

J. , C. Love, L. A. Estroff, J. K. Kriebel, R. G. Nuzzo et al., Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology, Chem. Rev, vol.105, issue.4, pp.1103-1170, 2005.

M. J. Hostetler, A. C. Templeton, and R. W. Murray, Dynamics of Place-Exchange Reactions on Monolayer-Protected Gold Cluster Molecules, Langmuir, vol.15, issue.11, pp.3782-3789, 1999.
DOI : 10.1021/la981598f

Z. Deng, Y. Tian, A. E. Seung-hyun-lee, C. Ribbe, and . Mao, DNA-Encoded Self-Assembly of Gold Nanoparticles into One-Dimensional Arrays, Angewandte Chemie, vol.19, issue.23, pp.3648-3651, 2005.
DOI : 10.1002/ange.200463096

K. Suzuki, K. Hosokawa, and M. Maeda, Controlling the Number and Positions of Oligonucleotides on Gold Nanoparticle Surfaces, Journal of the American Chemical Society, vol.131, issue.22, pp.7518-7519, 2009.
DOI : 10.1021/ja9011386

A. J. Mastroianni, S. A. Claridge, and A. Paul-alivisatos, Pyramidal and Chiral Groupings of Gold Nanocrystals Assembled Using DNA Scaffolds, Journal of the American Chemical Society, vol.131, issue.24, pp.8455-8459, 2009.
DOI : 10.1021/ja808570g

J. Sharma, R. Chhabra, A. Cheng, J. Brownell, Y. Liu et al., Control of Self-Assembly of DNA Tubules Through Integration of Gold Nanoparticles, Science, vol.323, issue.5910, pp.112-116, 2009.
DOI : 10.1126/science.1165831

S. Bidault, F. J. García-de-abajo, and A. Polman, Plasmon-Based Nanolenses Assembled on a Well-Defined DNA Template, Journal of the American Chemical Society, vol.130, issue.9, pp.2750-2751, 2008.
DOI : 10.1021/ja711074n

Z. Li, R. Jin, C. A. Mirkin, and R. L. Letsinger, Multiple thiol-anchor capped DNA-gold nanoparticle conjugates, Nucleic Acids Research, vol.30, issue.7, pp.1558-1562, 2002.
DOI : 10.1093/nar/30.7.1558

A. B. Steel, R. L. Levicky, T. M. Herne, and M. J. Tarlov, Immobilization of Nucleic Acids at Solid Surfaces: Effect of Oligonucleotide Length on Layer Assembly, Biophysical Journal, vol.79, issue.2, pp.975-981, 2000.
DOI : 10.1016/S0006-3495(00)76351-X

P. Richard, D. Fahlman, and . Sen, DNA Conformational Switches as Sensitive Electronic Sensors of Analytes, J. Am. Chem. Soc, vol.124, issue.17, pp.4610-4616, 2002.

C. Nadrian and . Seeman, Biochemistry and Structural DNA Nanotechnology : An Evolving Symbiotic Relationship, Biochemistry, vol.42, issue.24, pp.7259-7269, 2003.

W. K. Paul and . Rothemund, Folding DNA to create nanoscale shapes and patterns, Nature, vol.440, issue.7082, pp.297-302, 2006.

H. Dietz, S. M. Douglas, and W. M. Shih, Folding DNA into Twisted and Curved Nanoscale Shapes, Science, vol.325, issue.5941, pp.725-730, 2009.
DOI : 10.1126/science.1174251

S. M. Douglas, H. Dietz, T. Liedl, B. Högberg, F. Graf et al., Self-assembly of DNA into nanoscale three-dimensional shapes, Nature, issue.7245, pp.459414-418, 2009.

M. Zuker, Mfold web server for nucleic acid folding and hybridization prediction, Nucleic Acids Research, vol.31, issue.13, pp.3406-3415, 2003.
DOI : 10.1093/nar/gkg595

A. Periasamy and R. Day, Molecular Imaging, FRET Microscopy and Spectroscopy, Journal of Biomedical Optics, vol.11, issue.6, 2011.
DOI : 10.1117/1.2388275

B. Dubertret, M. Calame, and A. J. Libchaber, Single-mismatch detection using gold-quenched fluorescent oligonucleotides, Nature Biotechnology, vol.19, issue.4, pp.365-370, 2001.
DOI : 10.1038/86762

Z. Gueroui and A. Libchaber, Single-Molecule Measurements of Gold-Quenched Quantum Dots, Physical Review Letters, vol.93, issue.16, p.166108, 2004.
DOI : 10.1103/PhysRevLett.93.166108

J. James, C. A. Storhoff, and . Mirkin, Programmed Materials Synthesis with DNA, Chem. Rev, vol.99, issue.7, pp.1849-1862, 1999.

T. , A. Taton, C. A. Mirkin, and R. L. Letsinger, Scanometric DNA Array Detection with Nanoparticle Probes, Science, vol.289, issue.5485, pp.1757-1760, 2000.

C. S. Jwa-min-nam, C. A. Thaxton, and . Mirkin, Nanoparticle-Based Bio-Bar Codes for the ultrasensitive Detection of Proteins, Science, vol.301, issue.5641, pp.1884-1886, 2003.

D. Kim, W. L. Daniel, and C. A. Mirkin, Microarray-Based Multiplexed Scanometric Immunoassay for Protein Cancer Markers Using Gold Nanoparticle Probes, Analytical Chemistry, vol.81, issue.21, pp.9183-9187, 2009.
DOI : 10.1021/ac9018389

X. Xu, W. L. Daniel, W. Wei, and C. A. Mirkin, Detection Using DNA-Modified Gold-Nanoparticle Aggregates as Probes and Click Chemistry, Small, vol.131, issue.5, pp.623-626, 2010.
DOI : 10.1002/smll.200901691

J. Lee and C. A. Mirkin, Chip-Based Scanometric Detection of Mercuric Ion Using DNA-Functionalized Gold Nanoparticles, Analytical Chemistry, vol.80, issue.17, pp.6805-6808, 2008.
DOI : 10.1021/ac801046a

D. Lim, K. Jeon, H. M. Kim, J. Nam, and Y. D. Suh, Nanogap-engineerable Raman-active nanodumbbells for single-molecule detection, Nature Materials, vol.58, issue.1, pp.60-67, 2010.
DOI : 10.1038/nmat2596

D. Graham, D. G. Thompson, W. Smith, and K. Faulds, Control of enhanced Raman scattering using a DNA-based assembly process of dye-coded nanoparticles, Nature Nanotechnology, vol.72, issue.9, pp.548-551, 2008.
DOI : 10.1038/nnano.2008.189

G. P. Acuna, F. M. Möller, P. Holzmeister, S. Beater, B. Lalkens et al., Fluorescence Enhancement at Docking Sites of DNA-Directed Self-Assembled Nanoantennas, Science, vol.338, issue.6106, pp.338506-510, 2012.
DOI : 10.1126/science.1228638

P. Mickaël, B. Busson, B. Rolly, N. Stout, S. Bonod et al., Accelerated single photon emission from dye molecule-driven nanoantennas assembled on DNA, Nat Commun, vol.3, p.962, 2012.

J. J. Storhoff, R. Elghanian, C. A. Mirkin, and R. L. Letsinger, Sequence-Dependent Stability of DNA-Modified Gold Nanoparticles, Langmuir, vol.18, issue.17, pp.6666-6670, 2002.
DOI : 10.1021/la0202428

W. J. Parak, T. Pellegrino, C. M. Micheel, D. Gerion, S. C. Williams et al., Conformation of Oligonucleotides Attached to Gold Nanocrystals Probed by Gel Electrophoresis, Nano Letters, vol.3, issue.1, pp.33-36, 2003.
DOI : 10.1021/nl025888z

J. G. Gordon, I. , and S. Ernst, Surface plasmons as a probe of the electrochemical interface, Surface Science, vol.101, issue.1-3, pp.499-506, 1980.
DOI : 10.1016/0039-6028(80)90644-5

C. Nylander, B. Liedberg, and T. Lind, Gas detection by means of surface plasmon resonance, Sensors and Actuators, vol.3, pp.79-88, 1982.
DOI : 10.1016/0250-6874(82)80008-5

M. Kathryn, J. H. Mayer, and . Hafner, Localized Surface Plasmon Resonance Sensors, Chem. Rev, vol.111, issue.6, pp.3828-3857, 2011.

T. R. Jensen, M. Duval-malinsky, C. L. Haynes, and R. P. Van-duyne, Nanosphere Lithography:?? Tunable Localized Surface Plasmon Resonance Spectra of Silver Nanoparticles, The Journal of Physical Chemistry B, vol.104, issue.45, pp.10549-10556, 2000.
DOI : 10.1021/jp002435e

S. Schultz, D. R. Smith, J. J. Mock, and D. A. Schultz, Single-target Références molecule detection with nonbleaching multicolor optical immunolabels, pp.996-1001, 2000.

J. Yguerabide and E. E. Yguerabide, Light-Scattering Submicroscopic Particles as Highly Fluorescent Analogs and Their Use as Tracer Labels in Clinical and Biological Applications, Analytical Biochemistry, vol.262, issue.2, pp.137-156, 1998.
DOI : 10.1006/abio.1998.2759

K. J. Lee, D. Prakash, L. M. Nallathamby, C. J. Browning, X. Osgood et al., Imaging of Transport and Biocompatibility of Single Silver Nanoparticles in Early Development of Zebrafish Embryos, ACS Nano, vol.1, issue.2, pp.133-143, 2007.
DOI : 10.1021/nn700048y

C. Ranjit-yonzon, E. Jeoung, S. Zou, G. C. Schatz, M. Mrksich et al., A comparative Analysis of Localized and Propagating Surface Plasmon Resonance Sensors : The Binding of Concanavalin A to a Monosaccharide Functionalized Self-Assembled Monolayer, J. Am. Chem. Soc, issue.39, pp.12612669-12676, 2004.

A. J. Haes, L. Chang, W. L. Klein, and R. P. Van-duyne, Detection of a Biomarker for Alzheimer's Disease from Synthetic and Clinical Samples Using a Nanoscale Optical Biosensor, Journal of the American Chemical Society, vol.127, issue.7, pp.2264-2271, 2005.
DOI : 10.1021/ja044087q

L. Roberto-de, M. M. Rica, and . Stevens, Plasmonic ELISA for the ultrasensitive detection of disease biomarkers with the naked eye, Nat Nano, vol.7, issue.12, pp.821-824, 2012.

L. Rodríguez-lorenzo, R. De-la-rica, A. Ramón, L. M. Álvarez-puebla, M. M. Liz-marzán et al., Plasmonic nanosensors with inverse sensitivity by means of enzyme-guided crystal growth, Nature Materials, vol.315, issue.7, pp.604-607, 2012.
DOI : 10.1038/nmat3337

Y. Chen and C. Mao, pH-Induced Reversible Expansion/Contraction of Gold Nanoparticle Aggregates, Small, vol.8, issue.12, pp.2191-2194, 2008.
DOI : 10.1002/smll.200800569

P. Hazarika, B. Ceyhan, and C. M. Niemeyer, Reversible Switching of DNA-Gold Nanoparticle Aggregation, Angewandte Chemie, vol.72, issue.47, pp.6631-6633, 2004.
DOI : 10.1002/ange.200461887

W. Zhao, W. Chiuman, J. C. Lam, S. A. Mcmanus, W. Chen et al., DNA Aptamer Folding on Gold Nanoparticles:?? From Colloid Chemistry to Biosensors, Journal of the American Chemical Society, vol.130, issue.11, pp.3610-3618, 2008.
DOI : 10.1021/ja710241b

P. David, A. Fromm, P. J. Sundaramurthy, G. Schuck, W. E. Kino et al., Gap-Dependent Optical Coupling of Single " Bowtie " Nanoantennas Resonant in the Visible, Nano Lett, vol.4, issue.5, pp.957-961, 2004.

F. Lee and . Chen, A nanoplasmonic molecular ruler for measuring nuclease activity and DNA footprinting, Nat Nano, vol.1, issue.1, pp.47-52, 2006.

R. Verdoold, R. Gill, F. Ungureanu, R. Molenaar, and R. P. Kooyman, Femtomolar DNA detection by parallel colorimetric darkfield microscopy of functionalized gold nanoparticles, Biosensors and Bioelectronics, vol.27, issue.1, pp.77-81, 2011.
DOI : 10.1016/j.bios.2011.06.019

R. Lynell, B. M. Skewis, and . Reinhard, Spermidine Modulated Ribonuclease Activity Probed by RNA Plasmon Rulers, Nano Lett, vol.8, issue.1, pp.214-220, 2008.

H. Wang and B. M. Reinhard, Monitoring Simultaneous Distance and Orientation Changes in Discrete Dimers of DNA Linked Gold Nanoparticles, The Journal of Physical Chemistry C, vol.113, issue.26, pp.11215-11222, 2009.
DOI : 10.1021/jp900874n

Y. Kwang-lee, S. Kim, and J. Nam, Dark-Field-Based Observation of Single-Nanoparticle Dynamics on a Supported Lipid Bilayer for In Situ Analysis of Interacting Molecules and Nanoparticles, ChemPhysChem, 2014.

J. Aaron, K. Travis, N. Harrison, and K. Sokolov, Dynamic Imaging of Molecular Assemblies in Live Cells Based on Nanoparticle Plasmon Resonance Coupling, Nano Letters, vol.9, issue.10, pp.3612-3618, 2009.
DOI : 10.1021/nl9018275

M. J. Crow, K. Seekell, J. H. Ostrander, and A. Wax, Monitoring of Receptor Dimerization Using Plasmonic Coupling of Gold Nanoparticles, ACS Nano, vol.5, issue.11, pp.8532-8540, 2011.
DOI : 10.1021/nn201451c

W. Qian, X. Huang, B. Kang, and M. A. El-sayed, Dark-field light scattering imaging of living cancer cell component from birth through division using bioconjugated gold nanoprobes, Journal of Biomedical Optics, vol.15, issue.4, pp.46025-046025, 2010.
DOI : 10.1117/1.3477179.5

D. S. Sebba, J. J. Mock, D. R. Smith, T. H. Labean, and A. A. Lazarides, Reconfigurable Core???Satellite Nanoassemblies as Molecularly-Driven Plasmonic Switches, Nano Letters, vol.8, issue.7, pp.1803-1808, 2008.
DOI : 10.1021/nl080029h

P. F. Xu, A. M. Hung, H. Noh, and J. N. Cha, Switchable Nanodumbbell Probes for Analyte Detection, Small, vol.111, issue.2, pp.228-232, 2013.
DOI : 10.1002/smll.201201721

L. Guo, A. R. Ferhan, H. Chen, C. Li, G. Chen et al., Distance-Mediated Plasmonic Dimers for Reusable Colorimetric Switches: A Measurable Peak Shift of More than 60 nm, Small, vol.82, issue.2, pp.234-240, 2013.
DOI : 10.1002/smll.201201061

S. M. Douglas, I. Bachelet, and G. M. Church, A Logic-Gated Nanorobot for Targeted Transport of Molecular Payloads, Science, vol.335, issue.6070, pp.831-834, 2012.
DOI : 10.1126/science.1214081

P. Aaron, N. R. Esser-kahn, S. R. Sottos, J. S. White, and . Moore, Programmable Microcapsules from Self-Immolative Polymers, J. Am. Chem. Soc, vol.132, issue.30, pp.10266-10268, 2010.

E. Seong-lee, D. Kim, Y. Seok-youn, K. T. Oh, and Y. H. Bae, A Virus-Mimetic Nanogel Vehicle, Angewandte Chemie International Edition, issue.13, pp.472418-2421, 2008.

J. Lee, P. Hernandez, J. Lee, A. O. Govorov, and N. A. Kotov, Exciton???plasmon interactions in molecular spring assemblies of nanowires and wavelength-based protein detection, Nature Materials, vol.19, issue.4, pp.291-295, 2007.
DOI : 10.1038/nmat1869

A. Faisal, H. F. Aldaye, and . Sleiman, Dynamic DNA Templates for Discrete Gold Nanoparticle Assemblies : Control of Geometry, Modularity, Write/Erase and Structural Switching, J. Am. Chem. Soc, vol.129, issue.14, pp.4130-4131, 2007.

R. P. Goodman, M. Heilemann, S. Doose, C. M. Erben, A. N. Kapanidis et al., Reconfigurable, braced, three-dimensional DNA nanostructures, Nature Nanotechnology, vol.20, issue.2, pp.93-96, 2008.
DOI : 10.1038/nnano.2008.3

S. J. Hurst, A. K. Lytton-jean, and C. A. Mirkin, Maximizing DNA Loading on a Range of Gold Nanoparticle Sizes, Analytical Chemistry, vol.78, issue.24, pp.8313-8318, 2006.
DOI : 10.1021/ac0613582

A. Abuchowski, T. Van-es, N. C. Palczuk, and F. F. Davis, Alteration of immunological properties of bovine serum albumin by covalent attachment of polyethylene glycol, J. Biol. Chem, vol.252, issue.11, pp.3578-3581, 1977.

M. Francesco, A. Veronese, and . Mero, The impact of PEGylation on biological therapies, BioDrugs, vol.22, issue.5, pp.315-329, 2008.

A. Shelley, H. W. Claridge, S. R. Liang, J. M. Basu, A. Fréchet et al., Isolation of Discrete Nanopaticle-DNA Conjugates for Plasmonic Applications, Nano Lett, vol.8, issue.4, pp.1202-1206, 2008.

J. Dubochet and A. W. Mcdowall, VITRIFICATION OF PURE WATER FOR ELECTRON MICROSCOPY, Journal of Microscopy, vol.188, issue.3, pp.3-4, 1981.
DOI : 10.1111/j.1365-2818.1981.tb02483.x

J. Dubochet, Cryo-EM-the first thirty years, Journal of Microscopy, vol.102, issue.3, pp.221-224, 2012.
DOI : 10.1111/j.1365-2818.2011.03569.x

A. R. Rudolph, K. L. Jungjohann, D. R. Wheeler, and S. M. Brozik, Drying Effect Creates False Assemblies in DNA-Coated Gold Nanoparticles as Determined Through In Situ Liquid Cell STEM, Microscopy and Microanalysis, vol.4, issue.02, pp.437-444, 2014.
DOI : 10.1021/la2048486

A. Kenneth, R. M. Taylor, and . Glaeser, Electron Diffraction of Frozen, Hydrated Protein Crystals, Science, vol.186, issue.4168, pp.1036-1037, 1974.

A. Kenneth, R. M. Taylor, and . Glaeser, Retrospective on the early development of cryoelectron microscopy of macromolecules and a prospective on opportunities for the future, Journal of Structural Biology, vol.163, issue.3, pp.214-223, 2008.

S. Park, A. A. Lazarides, J. J. Storhoff, L. Pesce, and C. A. Mirkin, The Structural Characterization of Oligonucleotide-Modified Gold Nanoparticle Networks Formed by DNA Hybridization, The Journal of Physical Chemistry B, vol.108, issue.33, pp.12375-12380, 2004.
DOI : 10.1021/jp040242b

B. Cognet and . Lounis, Absorption and scattering microscopy of single metal nanoparticles, Physical Chemistry Chemical Physics, vol.8, issue.30, p.3486, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00143921

A. Arbouet, D. Christofilos, N. Del-fatti, F. Vallée, J. R. Huntzinger et al., Direct Measurement of the Single-Metal-Cluster Optical Absorption, Physical Review Letters, vol.93, issue.12, p.93127401, 2004.
DOI : 10.1103/PhysRevLett.93.127401
URL : https://hal.archives-ouvertes.fr/hal-00305504

H. Li and L. Rothberg, Colorimetric detection of DNA sequences based on electrostatic interactions with unmodified gold nanoparticles, Proceedings of the National Academy of Sciences, vol.101, issue.39, pp.14036-14039, 2004.
DOI : 10.1073/pnas.0406115101

Y. Liu, M. K. Shipton, J. Ryan, E. D. Kaufman, S. Franzen et al., Synthesis, Stability, and Cellular Internalization of Gold Nanoparticles Containing Mixed Peptide???Poly(ethylene glycol) Monolayers, Analytical Chemistry, vol.79, issue.6, pp.2221-2229, 2007.
DOI : 10.1021/ac061578f

G. Antonios, F. S. Kanaras, K. Kamounah, C. J. Schaumburg, M. Kiely et al., Thioalkylated tetraethylene glycol : a new ligand for water soluble monolayer protected gold clusters, Chemical Communications, issue.20, pp.2294-2295, 2002.

L. Maus, O. Dick, H. Bading, J. P. Spatz, and R. Fiammengo, Conjugation of Peptides to the Passivation Shell of Gold Nanoparticles for Targeting of Cell-Surface Receptors, ACS Nano, vol.4, issue.11, pp.6617-6628, 2010.
DOI : 10.1021/nn101867w

P. Harder, M. Grunze, R. Dahint, G. M. Whitesides, and P. E. Laibinis, Molecular Conformation in Oligo(ethylene glycol)-Terminated Self-Assembled Monolayers on Gold and Silver Surfaces Determines Their Ability To Resist Protein Adsorption, The Journal of Physical Chemistry B, vol.102, issue.2, pp.426-436, 1998.
DOI : 10.1021/jp972635z

G. Ralph, D. L. Nuzzo, and . Allara, Adsorption of bifunctional organic disulfides on gold surfaces, J. Am. Chem. Soc, vol.105, issue.13, pp.4481-4483, 1983.

C. Chi, F. Vargas-lara, A. V. Tkachenko, F. W. Starr, and O. Gang, Internal Structure of Nanoparticle Dimers Linked by DNA, ACS Nano, vol.6, issue.8, pp.6793-6802, 2012.
DOI : 10.1021/nn301528h

S. Srdjan, M. P. A?imovi?, M. U. Kreuzer, R. González, and . Quidant, Plasmon Near-Field Coupling in Metal Dimers as a Step toward Single-Molecule Sensing, ACS Nano, vol.3, issue.5, pp.1231-1237, 2009.

J. Liu and Y. Lu, Fast Colorimetric Sensing of Adenosine and Cocaine Based on a General Sensor Design Involving Aptamers and Nanoparticles, Angewandte Chemie, vol.42, issue.1, pp.96-100, 2006.
DOI : 10.1002/ange.200502589

I. L. Jennifer, H. Chen, B. Durkee, D. S. Traxler, and . Ginger, Optical Detection of Protein in Complex Media with Plasmonic Nanoparticle Dimers, Small, vol.7, issue.14, pp.1993-1997, 2011.

J. Wang, S. V. Boriskina, H. Wang, and B. M. Reinhard, Illuminating Epidermal Growth Factor Receptor Densities on Filopodia through Plasmon Coupling, ACS Nano, vol.5, issue.8, pp.6619-6628, 2011.
DOI : 10.1021/nn202055b

J. Wang, X. Yu, S. V. Boriskina, and B. M. Reinhard, Quantification of Differential ErbB1 and ErbB2 Cell Surface Expression and Spatial Nanoclustering through Plasmon Coupling, Nano Letters, vol.12, issue.6, pp.3231-3237, 2012.
DOI : 10.1021/nl3012227

D. Tabor and R. H. Winterton, The Direct Measurement of Normal and Retarded van der Waals Forces, Proc. R. Soc. Lond. A, pp.312435-450, 1969.
DOI : 10.1098/rspa.1969.0169

P. Tabeling, Introduction to Microfluidics, 2010.

F. Ungureanu, J. Halamek, R. Verdoold, and R. P. Kooyman, The use of a colour camera for quantitative detection of protein-binding nanoparticles, Plasmonics in Biology and Medicine VI, pp.71920-71920, 2009.
DOI : 10.1117/12.806522

F. Ungureanu, D. Wasserberg, N. Yang, R. Verdoold, and R. P. Kooyman, Immunosensing by colorimetric darkfield microscopy of individual gold nanoparticle-conjugates, Sensors and Actuators B: Chemical, vol.150, issue.2, pp.529-536, 2010.
DOI : 10.1016/j.snb.2010.08.044

P. Mickaël, S. Busson, and . Bidault, Selective Excitation of Single Molecules Coupled to the Bright Mode of a Plasmonic Cavity, Nano Lett, vol.14, issue.1, pp.284-288, 2014.

M. Hollander, D. A. Wolfe, and E. Chicken, Nonparametric Statistical Methods, 2013.
DOI : 10.1002/9781119196037

A. Kuzyk, R. Schreiber, Z. Fan, G. Pardatscher, E. Roller et al., DNA-based self-assembly of chiral plasmonic nanostructures with tailored optical response, Nature, vol.306, issue.7389, pp.483311-314, 2012.
DOI : 10.1038/nature10889

H. Soo and C. , Nanoparticle assembly : Building blocks for tumour delivery, Nat Nano, vol.9, issue.2, pp.93-94, 2014.

Y. T. Leo, K. Chou, W. C. Zagorovsky, and . Chan, DNA assembly of nanoparticle superstructures for controlled biological delivery and elimination, Nat Nano, vol.9, issue.2, pp.148-155, 2014.

J. Nam, N. Won, H. Jin, H. Chung, and S. Kim, pH-Induced Aggregation of Gold Nanoparticles for Photothermal Cancer Therapy, Journal of the American Chemical Society, vol.131, issue.38, pp.13639-13645, 2009.
DOI : 10.1021/ja902062j

S. Song, Z. Liang, J. Zhang, L. Wang, G. Li et al., Gold-Nanoparticle-Based Multicolor Nanobeacons for Sequence-Specific DNA Analysis, Angewandte Chemie International Edition, issue.46, pp.488670-8674, 2009.

Y. Lee, N. B. Schade, L. Sun, J. A. Fan, M. M. Doo-ri-bae et al., Ultrasmooth, Highly Spherical Monocrystalline Gold Particles for Precision Plasmonics, ACS Nano, vol.7, issue.12, pp.11064-11070, 2013.
DOI : 10.1021/nn404765w