Presentation

L’IRSAMC (The Institute of Research on Complex Atomic and Molecular Systems) is a federation of four laboratories (LCAR, LCPQ, LPCNO, LPT), in physics and fundamental chemistry whose research activities are supported both by the Université Paul Sabatier, the CNRS and INSA

Publications of 4 research laboratories

  • Hal-LCAR. - Laboratory Collisions Clusters Reactivity, from 1990 until todays
  • Hal-LCPQ. - Quantum Chemistry and Physics Laboratory, from 2007 until todays
  • Hal-LPCNO. - Physics and Chemistry of Nano Objects Laboratory, from 2006 until todays
  • Hal-LPT.- Theoretical Physics Laboratory, from 2003 until todays

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Last submission

[cea-02490702] NHC-Stabilized Iridium Nanoparticles as Catalysts in Hydrogen Isotope Exchange Reactions of Anilines  (26/02/2020)  
The preparation of N-heterocyclic carbene-stabilized iridium nanoparticles and their application in hydrogen isotope exchange reactions is reported. These air-stable and easy-to-handle iridium nanoparticles showed a unique catalytic activity, allowing selective and efficient hydrogen isotope incorporation on anilines using D-2 or T-2 as isotopic source. The usefulness of this transformation has been demonstrated by the deuterium and tritium labeling of diverse complex pharmaceuticals.

[hal-01327047] Pivotal Role of a Pentacoordinate 3MC State on the Photocleavage Efficiency of a Thioether Ligand in Ruthenium(II) Complexes: A Theoretical Mechanistic Study  (25/02/2020)  
[cea-02487414] Hydrogen Isotope Exchange Catalyzed by Ru Nanocatalysts: Labelling of Complex Molecules Containing N-Heterocycles and Reaction Mechanism Insights  (26/02/2020)  
[hal-02486540] Floquet thermalisation in a Rydberg-blockaded atomic chain subject to a frequency-modulated drive  (22/02/2020)  
[hal-02485688] Variational principles in quantum Monte Carlo: the troubled story of variance minimization  (22/02/2020)  

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